There is a reason why wheat, rice, and corn are the world's most popular grains. For those who have to avoid them, it can be a challenge to find adequate replacements. For smaller uses like sauce thickening, each item can be used on it's own. Usually, it takes a combination of alternate flours to get similar effects for larger quantities like in baking. Here are some combinations I've found useful:
Jo's All Purpose Flour, from Food Allergy Survival Guide
(The flour I use to make Chapatis)
3C tapioca starch
2C bean flour
2C sorghum flour
1C arrowroot
All Purpose Flour, from Cooking Free
1 1/2C sorghum flour
1/2C bean flour
1 1/2C potato starch
1 C tapioca starch
Bread Flour, from Allergen Free Baking
1 1/2C buckwheat flour (not actually related to wheat!)
1 1/2C sorghum flour
2C tapioca starch
1C potato starch
Muffin Mix, from Cooking Free
4C potato starch
3 1/3C bean flour
1C sorghum flour
1C tapioca starch
2C sugar
4t gelatin powder
3 1/2t salt
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